Lightweight and anisotropic cellulose nanofibril/rectorite composite sponges for efficient dye adsorption and selective separation

Constructing lightweight and porous adsorbents which can effectively remove dye contaminants is of great significance in the field of the sewage treatment. In this work, anisotropic cellulose nanofibril (CNF) composite sponges assisted by rectorites are fabricated through directional freeze-drying. The resulted composite sponge exhibits the superior saturated adsorption capacity and removal efficiency of 120.0 mg/g and 96.1% for methylene blue (MB), respectively, which is better than the pure CNF sponge and rectorite powders. This is attributed to the strong electrostatic interaction between CNFs and MB, and good cation exchange property of rectorites inside the three-dimensional (3D) highly porous composite sponge. The MB adsorption process of the composite sponge fits to the pseudo-second-order kinetic model and the Langmuir isotherm model well, which is affected by both boundary layer and intraparticle diffusion, resulting in a theoretical maximum adsorption capacity of 214.6 mg/g. Moreover, it also possesses a selective adsorption capacity for anionic and cationic dyes, which is expected to realize the separation treatment of different dyes according to actual application requirements.

Automated summary

Constructing lightweight and porous adsorbents for effective dye removal is crucial in sewage treatment. This study fabricated anisotropic cellulose nanofibril (CNF) composite sponges assisted by rectorites through directional freeze-drying. The resulting composite sponge exhibited superior adsorption capacity and removal efficiency, and showed selective adsorption ability for different dyes.