Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 142, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2022.109595
Keywords
cis-beta; Dinuclear; Ruthenium Schiff base
Categories
Funding
- Natural science fund for colleges and universities in Jiangsu Province [18KJB150007]
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Salen ligand L1 reacts with Ru-3(CO)(12) to form two complexes: a normal cis-beta-[Ru-II(salen)(L1)(CO)(2)] complex and a novel alkoxo-bridged dinuclear ruthenium schiff-base complex. The structures of both complexes have been determined by X-ray structure analysis. The dinuclear ruthenium complex is an efficient catalyst for intramolecular cyclopropanation of trans-alkenes.
Salen ligand L1 reacts with Ru-3(CO)(12) to give a normal cis-beta-[Ru-II(salen)(L1)(CO)(2)] complex and also a novel alkoxo-bridged dinuclear ruthenium schiff-base complex. Both complexes has been isolated as pure crystalline solids in moderate yields and their structures have been fully established by X-ray structure analysis. The dinuclear ruthenium complex was found to be an efficient catalyst for intramolecular cyclopropanation of trans-alkenes.
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