4.7 Article

Ternary Co-Ni sulfides deposited on Co(OH)2 nanoflakes decorated carbon cloth as electrode for supercapacitor

Journal

INORGANIC CHEMISTRY COMMUNICATIONS
Volume 140, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.inoche.2022.109443

Keywords

Co-Ni sulfides; Co(OH)(2) nanoflakes; Electrochemical performance; Supercapacitor; High specific capacitance

Funding

  1. National Natural Science Foundation of China [52102296, 52002293, 52172227]
  2. Graduate Innovation Fund of Wuhan Institute of Technology [CX2021183]

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The modification of carbon cloth with Co(OH)2 nanoflakes improves the electrochemical performance of Co-Ni-S for higher specific capacitance.
The ternary Co-Ni sulfides (Co-Ni-S) with earth-abundance, environmental friendliness, and high theoretical capacitance have been widely investigated in the field of pseudocapacitive supercapacitors. To further improve the utilization of Co-Ni-S to realize higher capacitance, Co-Ni-S was electrodeposited on carbon cloth (CC) that was modified by Co(OH)(2) nanoflakes (CC@Co(OH)(2) @Co-Ni-S). The modification of CC with Co(OH)(2) exhibits rough surface, which is beneficial to the electrodeposition of Co-Ni-S, further improving the electrochemical performance. As a result, the specific capacitance of CC@Co(OH)(2) @Co-Ni-S is higher than that of CC@Co-Ni-S without Co(OH)(2) modification. Even after 5000 cycles, the specific capacitance of CC@Co(OH)(2) @Co-Ni-S is still about 22% higher than that of CC@Co-Ni-S.

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