4.7 Article

Highly dispersed active sites of Ni nanoparticles onto hierarchical reduced graphene oxide architecture towards efficient water oxidation

Journal

FUEL
Volume 312, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2021.122926

Keywords

Electrocatalytic activity; Hierarchical architecture; Nanocomposite; Ni/rGO

Funding

  1. Taif University, Taif-Saudi Arabia [TURSP-2020/32]

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In this study, a facile method was developed to fabricate Ni nanoparticles decorated over reduced graphene oxide (Ni/rGO) nanocomposite by an in-situ reduction process. The Ni/rGO exhibited exceptional catalytic activity and stability in water oxidation.
Herein, we reported a facile route to fabricate the Ni-NPs decorated over reduced graphene oxide (Ni/rGO) nanocomposite by an in-situ reduction method. It has been observed that the Ni/rGO drived the water oxidation at a very low overpotential of 1.42 V-RHE (eta = 190 mV). Furthermore, the robust catalyst presented an extraordinary porosity and imperious kinetics performance while showing a high time of flight (0.2 s(-1)), mass activity (28 A/g) and smaller value of Tafel slope (62 mVdec(-1)) at an applied potential of 0.35 V-RHE only. Ni/rGO also exhibited stable current density which leftovers sustained in alkaline water catalysis conducted for a prolonged time without any significant loss in catalytic efficiency. This outstanding catalytic activity of hierarchical Ni/rGO is comparable to avant-garde electrocatalytic material and even much better than the noble and transitional metal-centred eensy-weensy electrocatalytic assemblies with several drawbacks.

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