Journal
EUROPEAN POLYMER JOURNAL
Volume 169, Issue -, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2022.111137
Keywords
Spontaneous polymerization; Topochemical polymerization; Emission; pi-stacked polymer; Neutral platinum(II) complex
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Benzofulvene derivatives bearing complexed and un-complexed pyridine rings were designed and synthesized to evaluate the impact of bulky substituents capable of establishing metallophilic interactions on the spontaneous solid-state polymerization.
Benzofulvene derivatives bearing complexed and un-complexed pyridine rings are designed and synthesized to assess the effects on the spontaneous solid-state polymerization of the presence in position 6 of the 3-phenylbenzofulvene moiety of bulky substituents capable of establishing metallophilic interactions. Both the benzofulvene monomers are found to polymerize spontaneously upon solvent removal under reduced pressure in the apparent absence of catalysts or initiators. The resulting polybenzofulvene derivatives are characterized by NMR spectroscopy, MALDI-TOF mass spectrometry, and in photophysical studies.
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