Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2022, Issue 29, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202200173
Keywords
S-arylsulfoximines; Dual photocatalysis; Fluorine; Heterocycles; Thioglycosides
Categories
Funding
- PRCI [ANR-17-CE07-0048-01]
- CNRS
- China Scholarship Council
- University-Paris-Saclay
- Agence Nationale de la Recherche (ANR)
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This study presents a general, scalable, and easy to implement protocol for synthesizing thiosugars and various ortho-functionalized compounds. The dual photocatalysis methodology using a commercial hydrogen atom transfer reagent resulted in the production of key structures, which were then transformed into original cyclic skeletons bearing previously undescribed chemical functions.
A general, scalable and easy to implement protocol is described for the coupling of thiosugars and various ortho-functionalized S-aryl S-perfluoroalkyl sulfoximines. This dual photocatalysis methodology was developed with a commercial hydrogen atom transfer reagent and produced key structures that were transformed into original cyclic skeletons bearing previously undescribed chemical functions.
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