4.5 Article

Synthesis of Chiral Ionic Liquids from Natural Monosaccharides

Journal

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2022, Issue 21, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202200100

Keywords

Benzimidazole; Carbohydrates; Imidazole; Ionic liquids; Pyrazole

Funding

  1. Regione Emilia-Romagna (Italy)
  2. Ecole Nationale Superieure de Chimie de Montpellier (France)

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This study investigates the anion-cation interactions and solvation shell of three series of new ionic liquids (ILs), prepared from low-cost, unprotected carbohydrates, using diffusion NMR and heteronuclear Overhauser correlation maps (HOESY).
Three series of new ionic liquids (ILs), namely imidazolium-, pyrazolium-, and bis-benzimidazolium-containing ILs, were prepared from low-cost, unprotected carbohydrates. Information on anion-cation interactions and solvation shell were obtained via diffusion NMR and heteronuclear Overhauser correlation maps (HOESY), respectively.

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