Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume 2022, Issue 18, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.202200037
Keywords
Activation of carbon dioxide; Carbon dioxide reduction; Cascade process; Metal organic frameworks; Pauson-Khand reaction
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Funding
- Ecole Polytechnique Federale de Lausanne
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This article describes the use of CO2 as a promising C1 source instead of CO in the tandem Pauson-Khand reaction. The reaction is achieved by combining the reduction of CO2 to CO using a metal organic framework (MOF) catalyst with homogeneous rhodium catalysts for the cycloaddition step. A range of substrates were converted in moderate to good yields.
We describe the use of CO2 as a promising C1 source instead of CO in the tandem Pauson-Khand reaction. The reaction is achieved by combining the reduction of CO2 to CO using a metal organic framework (MOF) catalyst with homogeneous rhodium catalysts for the cycloaddition step. A range of substrates were converted in moderate to good yields.
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