Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume 2022, Issue 16, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.202200106
Keywords
Iron; N-heterocyclic carbenes; Palladium; Selenium; Transmetalation
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Funding
- DFG [SFB/TRR 88]
- Projekt DEAL
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Starting from [(eta(5)-cyclopentadienyl)(eta(6)-phenyl)iron(II)]imidazole, dicationic imidazolium salts were prepared by N-alkylation, and mono respectively dicationic transition metal NHC complexes were obtained. Transmetalation using the copper(I) complexes opened up the access to NHC gold(I) compounds. The new NHC complexes were investigated by various analytical methods, and their catalytic properties were tested in different model reactions.
Starting from [(eta(5)-cyclopentadienyl)(eta(6)-phenyl)iron(II)]imidazole, dicationic imidazolium salts were prepared by N-alkylation. Reaction of these compounds with basic metal precursors such as mesityl copper(I) or palladium(II) acetate led to mono respectively dicationic transition metal NHC complexes (NHC=N-heterocyclic carbene). Transmetalation using the copper(I) complexes opened up the access to NHC gold(I) compounds. PEPPSI-type NHC complexes of palladium(II) and platinum(II) were prepared by offering a neutral pyridine ligand to the transition metal center. A rhodium(I) NHC complex was accessible by deprotonation of the dicationic imidazolium precursor and subsequent treatment with [(COD)Rh(mu(2)-Cl)](2) (COD=1,5-cyclooctadiene). The new NHC complexes were investigated by means of NMR spectroscopy, mass spectrometry as well as single crystal X-ray structure analysis. Both, the palladium(II) containing PEPPSI-type and the gold(I) complex, were investigated for their catalytic properties in typical model reactions such as cyclization reactions, Suzuki coupling and cyanation. In addition, a selenium adduct was synthesized in order to study the electronic properties of the underlying ligand backbone. Based on the chemical shift in the Se-77 NMR spectrum, it is evident that these NHC ligands possess rather poor pi-acidity.
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