Natural kaolinite-based hierarchical porous microspheres as effective and highly recyclable adsorbent for removal of cationic dyes

The development of efficient, recyclable, and environment-friendly adsorbent for wastewater remediation is considered a challenge. In this study, a hierarchical porous kaolinite microsphere (HPKS) with three-dimensional (3D) structure was fabricated based on natural-layered kaolinite mineral via an environmentally friendly direct hydrothermal strategy. Characterization results revealed that HPKS microsphere with 3D hierarchical porous structure was constructed with numerous nanospheres which are assembled by ultrafine aluminosilicate flakes. HPKS exhibited negative charge feature ranging from strong acid to high alkaline solution. The influence of contact time, solution pH, initial dye concentration, adsorbent dosage, and foreign ions on methylene blue (MB) adsorption capability was systematically investigated. The synthesized HPKS with higher specific surface area (250.6 m(2) /g) shows an outstanding adsorption capacity towards MB (411.8 mg/g) and excellent selectivity for cationic MB dyes over anionic methyl orange and competitive metal ions. The adsorption kinetic experiment results fit very well with the pseudo-second-order model and reflect the fast adsorption rate of MB on HPKS. The sorption isotherm study reveals the chemisorption of electrostatic attraction between the cationic MB molecules and the negative charged surfaces of HPKS. More importantly, the MB removal efficiency is more than 99% in a broad range of solution pH value. The adsorption capacities of HPKS can be easily recovered by calcination at 600 degrees C to remove the adsorbed dyes and without obvious diminishment even after six successive cycles. Therefore, the HPKS is a cost-effective and environmentally friendly adsorbent which has is promising to use in practical applications.

Automated summary

In this study, hierarchical porous kaolinite microsphere (HPKS) with three-dimensional structure was successfully fabricated as an efficient and environmentally friendly adsorbent for wastewater remediation. The synthesized HPKS exhibited excellent adsorption capacity for methylene blue (MB) and high selectivity for cationic MB dyes. The adsorption kinetic experiment results fit well with the pseudo-second-order model, indicating a fast adsorption rate. The sorption isotherm study revealed the chemisorption of electrostatic attraction between the cationic MB molecules and the negative charged surfaces of HPKS. Furthermore, HPKS showed high stability and recyclability through calcination without obvious diminishment of adsorption capacity.