Current and Future Trends of Low and High Molecular Weight Polycyclic Aromatic Hydrocarbons in Surface Water and Sediments of China: Insights from Their Long-Term Relationships between Concentrations and Emissions

In this study, we analyzed the temporal trend of polycyclic aromatic hydrocarbons (PAHs) in China using data reported over the past 20 years. We found that the total concentrations of low molecular weight PAHs (C-Sigma LPHs) in surface water and sediments were positively correlated with their total emissions (C-Sigma LPHs), which increased between 2000 and 2008, then decreased until 2017. Additionally, the total concentrations of high molecular weight PAHs (C-Sigma LPHs) in surface water and sediments were positively correlated with their total emissions (C-Sigma LPHs), which increased significantly from 2000 to 2014 and then plateaued. Two future scenarios were assessed to explore C-Sigma LPHs and C-Sigma LPHs s in surface water and sediments. PAH emissions were reduced by technological improvement in 2030 for coal consumption in Scenario 1 and for control of biomass burning in Scenario 2. Scenario 1 was more efficient than Scenario 2 in reducing C-Sigma LPHs in the surface water and sediments of China for the areas where C-Sigma LPHs in surface water exceeded the annual average standard (i.e., 30 ng L-1), with reductions of 38 and 24% in Scenarios 1 and 2, respectively. The observed relationships in this study can provide tools for emission reduction policies in the future.

Automated summary

This study analyzed the temporal trend of PAHs in China over the past 20 years and found a positive correlation between the concentrations of low and high molecular weight PAHs and their total emissions. By assessing future scenarios, the study showed that technological improvement and control of biomass burning can effectively reduce PAH emissions.