4.7 Article

Catalase-integrated metal-organic framework with synergetic catalytic activity for colorimetric sensing

Journal

ENVIRONMENTAL RESEARCH
Volume 207, Issue -, Pages -

Publisher

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.envres.2021.112147

Keywords

Catalase; Fe-BTC; Peroxidase-like activity; Colorimetric sensing; Hydrogen peroxide; Phenol

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This study encapsulates catalase in MOFs, creating a stable composite, and demonstrates the application of MOFs combined with natural enzymes in efficient catalyst construction.
As a platform for enzyme immobilization, metal-organic frameworks (MOFs) can protect enzyme activity from the interference of external adverse environment. Although these strategies have been proven to produce good results, little consideration has been given to the functional similarity of MOFs to the encapsulated enzyme. Here, catalase (CAT) was encapsulated in Fe-BTC with peroxidase-like activity to obtain a stable composite (CAT@FeBTC) with synergistic catalytic activity. Depending on the superior selectivity and high catalytic activity of CAT@Fe-BTC, colorimetric sensing for the detection of hydrogen peroxide and phenol was developed. This work demonstrates that the integration of functional MOFs with natural enzyme can be well applied to the construction of efficient catalysts.

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