4.7 Article

Synthesis and fluorescence property modulation of α-cyano-1,4-diphenylbutadiene derivatives containing triphenylamine structure

Journal

DYES AND PIGMENTS
Volume 199, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2021.110077

Keywords

Triphenylamine; Fluorescence modulation; Intramolecular charge-transfer; Donor-acceptor structure

Funding

  1. National Natural Science Foundation of China [21572086, 21572085, 51733004, 22075117]
  2. Program for Changjiang Scholars and Innovative Research Team in University [PCSIRT: IRT_15R28]
  3. Fundamental Research Funds for the Central University [FRFCU: lzujbky-2016-ct02, lzujbky-2021-sp33]
  4. 111 Project of MOE [111-2-17]

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In this study, a series of alpha-cyano-1,4-diphenylbutadiene derivatives containing triphenylamine structure were designed and synthesized. By changing the connection mode, the fluorescent wavelengths of the compounds were further regulated.
ABS T R A C T In this paper, a series of alpha-cyano-1,4-diphenylbutadiene derivatives containing triphenylamine structure were designed and synthesized. By changing the connection mode of the terminal diphenylamine, the angle between the donor and the acceptor was adjusted to further regulate the fluorescent wavelengths of 1a-1h from 456 nm to 621 nm in solution and 515 nm-614 nm in solid states.

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