Journal
DYES AND PIGMENTS
Volume 200, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2022.110160
Keywords
First-hyperpolarizability; Intrinsic hyperpolarizability; Push-Pull chromophores; Fluorene; Hyper Rayleigh scattering; Second harmonic generation
Funding
- SERB (DST) [EMR/2017/000520]
- Guru Nanak Dev University, Amritsar
- UGC [(BSR) /CH/18-19/0321]
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The photophysical properties of a series of chromophores with push-pull type conjugation were studied to evaluate their potential as nonlinear optically active materials. The compounds showed promising first hyperpolarizability values and efficiency in nonlinear optical response, outperforming counterparts based on benzothiazole platform.
Photophysical properties including the first hyperpolarizability of a series of chromophores (SP1-SP5) possessing push-pull type conjugation were investigated to evaluate the proficiency as non-linear optically active materials. The compounds are based on the 9,9-dimethyl-9H-fluoren-2-amine platform, which acts as a donor unit and different types of acceptors have been incorporated to design SP1-SP5. The first hyperpolarizability (beta(HRS)) value was in the range of 102 x 10(-30) esu to 174 x 10(-30) esu, and the trends in the experimental beta(HRS) have been rationalized in terms of the difference in the dipole moment (delta mu(ge)) of the ground and excited state, oscillator strength of the contributing absorption bands and the band gaps. The intrinsic efficiency of the non-linear response of these dipolar compounds possessing a single major dipolar hyperpolarizability tensor component beta(zzz) was also determined from the intrinsic hyperpolarizability, a real figure of merit of the non-linear optical response. Comparison of the experimental off-resonant first hyperpolarizability, beta(HRS), as well as the intrinsic hyperpolarizability of this set of D-pi-A chromophores, lacking linear conjugation, revealed advantage over the already reported counterparts based on benzothiazole platform.
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