Superhydrophobic and superoleophilic PH-CNT membrane for emulsified oil-water separation

Extensive efforts have been devoted to oil-water separation in recent years, especially the separation of water-in oil emulsions. In this study, we report a superhydrophobic and superoleophilic PH-CNT (poly vinylidene fluoridehexafluoropropylene, carbon nanotubes) membrane with highly porous structures for oil-water separation. The membrane possesses hierarchically layered micro/nano-porous structures both on the membrane surface and inside the nanofibers. The membrane effectively separated surfactant stabilized water-in-oil emulsions with micro/nano droplets, demonstrating a separation efficiency above 99.5%, while also exhibiting excellent recyclability with good chemical and mechanical stability. The PH-CNT membrane holds great potential for the purification of emulsified oil-water mixtures from industrial and domestic sources.

Automated summary

In this study, a superhydrophobic and superoleophilic PH-CNT membrane with highly porous structures was developed for efficient separation of water-in-oil emulsions. The membrane demonstrated a separation efficiency above 99.5% and showed good recyclability with excellent chemical and mechanical stability. It holds great potential for the purification of emulsified oil-water mixtures from industrial and domestic sources.