4.8 Review

Metal nanocluster-based hybrid nanomaterials: Fabrication and application

Journal

COORDINATION CHEMISTRY REVIEWS
Volume 456, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2021.214391

Keywords

Metal nanocluster; Metal nanocluster-based hybrid nanomaterial; Dimension; Sensing; Biomedicine; Catalysis; Light emitting diode

Funding

  1. Thirteenth Five Year Project of Science and Technology Research in the Education Department of Jilin Province [40542]
  2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, China [2022-21]

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Metal nanocluster-based hybrid nanomaterials (MNCHNs) created by hybridizing metal nanoclusters with various components have shown promising optical, electrical, magnetic, and catalytic properties. This review summarizes the progress in the synthesis and application of MNCHNs in diverse fields, such as sensing, biomedicine, catalysis, and light emitting diode. The challenges and future research directions of MNCHNs are also discussed.
Metal nanoclusters (MNCs) with molecular-like structure have attracted widespread attention owing to their distinctive photoelectrical properties. However, the weak emission and instability of MNCs prevent their practical applications. In order to solve these problems, hybridizing MNCs with various components to prepare metal nanocluster-based hybrid nanomaterials (MNCHNs) has been confirmed to be an effec-tive strategy. In particular, the synergistic effect of MNCs and the introduced components affords MNCHNs with promising optical, electrical, magnetic, and catalytic properties. For the first time, this review summarizes the progress of MNCHNs in recent years, and focuses on the synthetic strategies for fabricating MNCHNs based on dimensions of the introduced components as well as their applications in various fields, such as sensing, biomedicine, catalysis, and light emitting diode. Moreover, we discuss the current challenges of MNCHNs and their future research directions.(c) 2021 Elsevier B.V. All rights reserved.

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