4.8 Review

Current Advances in the Sustainable Conversion of 5-Hydroxymethylfurfural into 2,5-Furandicarboxylic Acid

Related references

Note: Only part of the references are listed.
Article Agricultural Engineering

Use of filamentous fungi as biocatalysts in the oxidation of 5-(hydroxymethyl)furfural (HMF)

Derek Troiano et al.

Summary: This study explores the use of filamentous fungi as oxidative biocatalysts, focusing on the oxidation of HMF. Among the five fungal species tested, A. niger and T. reesei showed superior performance and potential for conversion into FDCA through a chemo-biocatalytic reaction system. The optimized one-pot chemo-biocatalytic cascade system achieved an 88% molar yield of FDCA after 80 hours.

BIORESOURCE TECHNOLOGY (2022)

Review Chemistry, Multidisciplinary

Electro- and Photocatalytic Oxidative Upgrading of Bio-based 5-Hydroxymethylfurfural

Ye Meng et al.

Summary: The conversion of biomass into biofuels and high-value chemicals is an important strategy for solving environmental problems. This review provides an overview of the progress and challenges in using HMF to produce high-value chemicals. The catalytic efficiency and mechanism of different catalysts are also discussed.

CHEMSUSCHEM (2022)

Review Biotechnology & Applied Microbiology

Recent advances in biotransformation of 5-Hydroxymethylfurfural: challenges and future aspects

Kongkona Saikia et al.

Summary: HMF bioconversion is a promising alternative to fossil-derived products through sustainable routes, with its higher selectivity, environment friendliness, and mild reaction conditions considered as advantages for commercialization.

JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY (2022)

Article Chemistry, Physical

Metal Single-Atom and Nanoparticle Double-Active-Site Relay Catalysts: Design, Preparation, and Application to the Oxidation of 5-Hydroxymethylfurfural

Shaowei Yang et al.

Summary: A Co-based double-active-site relay catalyst was reported for the aerobic oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA) with high efficiency, showing promise in the development of highly active catalysts for complex tandem reactions.

ACS CATALYSIS (2022)

Article Chemistry, Physical

Mechanistic insights into CoOx-Ag/CeO2 catalysts for the aerobic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid

Mengchen Fu et al.

Summary: This study achieved a high yield of FDCA synthesis through the synthesis of CoOx-Ag/CeO2 catalysts, and revealed the cooperative role of Ag+ and O-v-Ce3+ sites in the reaction process.

CATALYSIS SCIENCE & TECHNOLOGY (2022)

Article Chemistry, Physical

Whole Cell Biocatalysis of 5-Hydroxymethylfurfural for Sustainable Biorefineries

Joana T. Cunha et al.

Summary: This study focuses on the utilization of microorganisms as whole-cell biocatalysts for the production of 5-hydroxymethylfurfural (HMF) derivatives. While significant progress has been made in the conversion of HMF into 2,5-bis(hydroxymethyl)furan (BHMF), 2,5-furandicarboxylic acid (FDCA) and 5-hydroxymethyl-furan-2-carboxylic acid (HMFCA), there have been no reports on microbial production of 2,5-diformylfuran (DFF) and 5-formyl-2-furancarboxylic acid (FFCA). Genetic engineering strategies play a crucial role in the production of FDCA, while wild type microorganisms are mainly used for BHMF and HMFCA production.

CATALYSTS (2022)

Article Biotechnology & Applied Microbiology

Biotransformation of 5-hydroxymethylfurfural and furfural with bacteria of bacillus genus

Monica L. Becerra et al.

Summary: This study investigates the detoxification of furfural and 5-HMF using bacterial isolates from sugarcane bagasse. The results show that B. toyonensis is a useful strain for detoxifying lignocellulosic residues and producing furans with a high added value.

BIOCATALYSIS AND AGRICULTURAL BIOTECHNOLOGY (2022)

Article Agricultural Engineering

Recent advances in catalytic conversion of biomass derived 5-hydroxyme-thylfurfural into 2,5-furandicarboxylic acid

Jiawei Cai et al.

Summary: With the aggravation of global environmental problems and the shortage of fossil resources, finding environmentally friendly renewable chemicals and fuels to replace fossil resources has become particularly important. This review systematically summarizes the catalytic routes for the preparation of 5-hydroxymethylfurfural (HMF) from hexose and the production of 2,5-furandicarboxylic acid (FDCA) from HMF. The effects of different catalytic systems on the yield of target products are analyzed, and the limitations of current catalytic systems are discussed. Electrocatalysis and biocatalysis, based on green chemistry approaches, energy efficiency, mild reaction conditions, and high selectivity, are important for the effective utilization of biomass resources in the future.

BIOMASS & BIOENERGY (2022)

Article Green & Sustainable Science & Technology

Integrative technical, economic, and environmental sustainability analysis for the development process of biomass-derived 2,5-furandicarboxylic acid

H. Kim et al.

Summary: This study presents a new process design for economically producing FDCA from lignocellulosic biomass. The process maximizes the economics by introducing effective biomass fractionation method and minimizing energy consumption. The economic feasibility and environmental sustainability of the process were assessed through techno-economic analysis and life-cycle assessment.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2022)

Article Chemistry, Applied

A highly efficient and reusable Ru-NaY catalyst for the base free oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic acid

Prabu Kandasamy et al.

Summary: This study presents a Ru-NaY nanocatalyst for the oxidation of HMF to FDCA, showing superior catalytic activity under base free conditions and good recyclability. High metal dispersion and small size of Ru nanoparticles play vital roles in the reaction. Acidic hydroxyl groups in the supercage and higher amount of metallic Ru degrees are also responsible for the high yield and productivity of FDCA.

CATALYSIS TODAY (2021)

Article Chemistry, Physical

Hollow Zeolites Encapsulating Ultra-Low Noble Metal Nanoparticles for HMF Oxidation

Shilpi Saxena et al.

Summary: By encapsulating noble metal nanoparticles in zeolite nanocapsules, efficient oxidation of HMF was achieved with high yields of FDCA. The study revealed that MCM-22 loaded with gold nanoparticles exhibited the highest HMF conversion and FDCA yield.

CATALYSIS LETTERS (2021)

Article Biotechnology & Applied Microbiology

Characterization of a thermotolerant aryl-alcohol oxidase from Moesziomyces antarcticus oxidizing 5-hydroxymethyl-2-furancarboxylic acid

Alessa Lappe et al.

Summary: This study reports the heterologous expression of a new aryl-alcohol oxidase, MaAAO, from Moesziomyces antarcticus in Pichia pastoris at high yields, highlighting its broad acceptance of various alcohol substrates and high thermal stability. The application of MaAAO shows promising potential for the production of precursors for bioplastics and bioactive compounds.

APPLIED MICROBIOLOGY AND BIOTECHNOLOGY (2021)

Article Chemistry, Physical

Base-free oxidation of 5-hydroxymethylfurfural to 2, 5-furan dicarboxylic acid over nitrogen-containing polymers supported Cu-doped MnO2 nanowires

Jinhua Lai et al.

Summary: Cu-doped MnO2 nanowires supported on nitrogen-containing polymers were prepared as catalysts for the oxidation of HMF to FDCA. The catalyst showed excellent catalytic activity, with a high yield of FDCA. Intermediates were identified in the oxidation process, and it was found that oxidation of the hydroxyl group in HMF was easier than that of the aldehyde group.

APPLIED SURFACE SCIENCE (2021)

Article Engineering, Environmental

Nitrogen-doped carbon: A metal-free catalyst for selective oxidation of crude 5-hydroxymethylfurfural obtained from high fructose corn syrup (HFCS-90) to 2,5-furandicarboxylic acid (FDCA)

Kasanneni Tirumala Venkateswara Rao et al.

Summary: The team successfully synthesized an inexpensive nitrogen-doped carbon material and applied it in the oxidation reaction of converting 5-HMF into FDCA, achieving good conversion and yield rates, making significant progress in the field of biomass conversion.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Chemistry, Multidisciplinary

Highly Ordered Mesoporous Co3O4 Electrocatalyst for Efficient, Selective, and Stable Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid

Changlong Wang et al.

Summary: This study presents a 3D highly ordered mesoporous Co3O4/nickel foam electrode that achieves high efficiency, selectivity, and stability in the electrochemical oxidation of HMF to produce FDCA. The electrode demonstrates fast electron transfer, high electrochemical surface area, and reduced charge transfer resistance, leading to exceptional activity and selectivity towards FDCA.

CHEMSUSCHEM (2021)

Article Engineering, Chemical

Mechanistic kinetic modelling of enzyme-catalysed oxidation reactions of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA)

Misa Mojca Cajnko et al.

Summary: Six enzymes were tested for their specificity, product yield, and pathways in reactions with HMF and its oxidation intermediates; a Michaelis-Menten kinetic mathematical model was constructed with some rate parameters calculated; multi-enzyme reactions were used for model validation, revealing a small discrepancy between the measured and modeled reactions due to the exclusion of specific interactions in mechanisms.

CHEMICAL ENGINEERING SCIENCE (2021)

Article Engineering, Chemical

Efficient Aerobic Oxidation of 5-Hydroxymethylfurfural to 2, 5-Furandicarboxylic Acid over a Nanofiber Globule La-MnO2 Catalyst

Linhao Yu et al.

Summary: The La MnO2 catalyst demonstrates excellent performance in converting HMF to FDCA in water, with high selectivity and conversion rate.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2021)

Article Chemistry, Organic

Electrocatalytic Oxidation of Biomass-derived 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid Coupled with H2 Evolution

Ye Meng et al.

Summary: This study reviews the promising strategies of simultaneous electrocatalytic conversion of biomass into high-value products and water electrolysis for hydrogen production. Focus is placed on the recent advances in the electrocatalytic oxidation of HMF and water reduction to produce FDCA and hydrogen fuel. Oxidation of HMF to FDCA was found to be more thermodynamically and kinetically favorable than the Oxygen Evolution Reaction, with opportunities and challenges presented.

CURRENT ORGANIC CHEMISTRY (2021)

Article Chemistry, Physical

Experimental and Kinetic Study on the Production of Furfural and HMF from Glucose

Ouwen He et al.

Summary: In this study, the simultaneous production of furfural and HMF from glucose using a SnSO4-H2SO4 coupling catalyst in GVL solvent achieved promising results with high yields. Kinetics study showed that the production rate ratio of furfural to HMF remained constant close to 1 at different temperatures and GVL/water ratios, indicating similar reaction pathways for furfural and HMF production. Based on experimental and kinetics studies, a proposed reaction pathway for glucose conversion to furfural and HMF was established.

CATALYSTS (2021)

Review Chemistry, Physical

Recent Advances in Photocatalytic Oxidation of 5-Hydroxymethylfurfural

Chenchen Li et al.

Summary: This review discusses the application of photocatalyst systems in HMF oxidation, focusing on catalyst material design, product selectivity, mechanistic insight, and catalyst stability. The aim is to inspire researchers to develop efficient photocatalyst systems for solar biorefinery.

CHEMPHOTOCHEM (2021)

Review Chemistry, Applied

2,5-Furandicarboxylic acid production via catalytic oxidation of 5-hydroxymethylfurfural: Catalysts, processes and reaction mechanism

Chunlin Chen et al.

Summary: The conversion of biomass into value-added chemicals, particularly using 5-hydroxymethylfurfural as a key platform molecule, has garnered significant attention. The oxidation product 2,5-furandicarboxylic acid shows promise as an alternative to petroleum-based terephthalic acid for the synthesis of biodegradable plastics.

JOURNAL OF ENERGY CHEMISTRY (2021)

Article Chemistry, Physical

Base-free atmospheric O2-mediated oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic acid triggered by Mg-bearing MTW zeolite supported Au nanoparticles

Lei Chen et al.

Summary: The MgSi-ZSM-12 catalyst showed excellent activity for the oxidation of HMF into FDCA in the presence of atmospheric dioxygen without the need for externally adding any liquid base. The catalyst exhibited strong adsorption of HMF but negligible adsorption of FDCA, accelerating the production of FDCA under base-free conditions.

APPLIED CATALYSIS A-GENERAL (2021)

Article Chemistry, Applied

Base-free selective conversion of 5-hydroxymethylfurfural to 2,5-furandi-carboxylic acid over a CoOx-CeO2 catalyst

Mengmeng Jin et al.

Summary: Different molar ratios of Co/Ce in Ce oxide-based catalysts significantly affect the oxidation of 5-HMF to FDCA, with the CoCe-0.15 catalyst showing high activity and selectivity at 130 degrees C. The reaction mechanism involves Mars-van Krevelen mechanism with redox of Ce4+/Ce3+ and Co3+/Co2+ for lattice oxygen replenishment.

CATALYSIS TODAY (2021)

Article Chemistry, Physical

Engineered Stable 5-Hydroxymethylfurfural Oxidase (HMFO) from 8BxHMFO Variant of Methylovorus sp. MP688 through B-Factor Analysis

Qiuyang Wu et al.

Summary: The research successfully engineered stability-enhanced HMFO from 8BxHFMO, and identified two effective mutants, Q319K and N44G, which exhibited improved FDCA yield and stability at higher reaction temperatures. The mutants show potential for enhancing the design of more stable biocatalysts and optimizing the utilization of HMFO in biotechnological processes.

CATALYSTS (2021)

Article Chemistry, Physical

Hierarchical porous bowl-like nitrogen-doped carbon supported bimetallic AuPd nanoparticles as nanoreactors for high efficient catalytic oxidation of HMF to FDCA

Wen Guan et al.

Summary: Hierarchical porous bowl-like nitrogen-doped carbon supported AuPd bimetallic nanoreactors were successfully synthesized and used for the efficient catalytic oxidation of HMF to FDCA, achieving a high yield of 97.6%. The rate-determining step was confirmed to be the oxidation of FFCA to FDCA, and regeneration experiments showed that the nanoreactors could be recycled and reused multiple times without losing catalytic activity.

JOURNAL OF CATALYSIS (2021)

Article Nanoscience & Nanotechnology

Pt Nanoparticles on ZSM-5 Nanoparticles for Base-Free Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid

Saros Salakhum et al.

Summary: A method for the selective oxidation of HMF to FDCA and its derivatives was achieved using highly dispersed Pt nanoparticles supported on alkaline-exchanged hierarchical ZSM-5 nanoparticles. By conducting the reaction in a base-free aqueous-phase system, a high HMF conversion rate of 100% and FDCA selectivity of 80% were achieved.

ACS APPLIED NANO MATERIALS (2021)

Article Chemistry, Multidisciplinary

Tailoring the Reactive Oxygen Species in Mesoporous NiO for Selectivity-Controlled Aerobic Oxidation of 5-Hydroxymethylfurfural on a Loaded Pt Catalyst

Hao Zhang et al.

Summary: A mesoporous NiO-supported Pt nanoparticle catalyst demonstrated efficient and sustainable conversion of HMF to FDCA without the need for a base. By tailoring the reactive oxygen species in NiO, the initial reaction rate of HMF and product distribution could be effectively controlled. The interaction between metallic Pt active sites and mobile oxygen species was crucial for the excellent catalytic performance observed.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

Article Engineering, Chemical

Solvent- and Base-Free Oxidation of 5-Hydroxymethylfurfural over a PdO/AlPO4-5 Catalyst under Mild Conditions

Linhao Yu et al.

Summary: A solvent-free method was proposed to upgrade biomass-derived compound 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA) with high selectivity. The oxidation of HMF to FDCA without solvent and base addition, with O-2 replenishing the consumption of active oxygen species on the catalyst surface, demonstrated a successful reaction mechanism.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2021)

Article Biotechnology & Applied Microbiology

Optimizing operational parameters for the enzymatic production of furandicarboxylic acid building block

Maria Isabel Sanchez-Ruiz et al.

Summary: This study analyzed the factors affecting the performance of HMFO in oxidizing HMF, revealing a significant influence of pH on enzyme activity and different optimal pH values for improved variants. The enzymes were found to be unstable at high hydrogen peroxide concentrations and inhibited by the FFCA intermediate, which could be efficiently addressed with catalase addition and controlled substrate dosage. The different behavior of wild-type HMFO and its variants against pH, hydrogen peroxide, and FFCA highlights the importance of considering each variant as an individual enzyme with its own operational conditions for potential industrial FDCA production.

MICROBIAL CELL FACTORIES (2021)

Article Multidisciplinary Sciences

Toward scalable biocatalytic conversion of 5-hydroxymethylfurfural by galactose oxidase using coordinated reaction and enzyme engineering

William R. Birmingham et al.

Summary: Researchers have successfully engineered a galactose oxidase variant with high activity towards 5-hydroxymethylfurfural (HMF), improved oxygen binding, and high productivity. This advancement presents a promising biocatalytic route to scalable production of furan-based chemical building blocks from sustainable feedstocks.

NATURE COMMUNICATIONS (2021)

Article Chemistry, Physical

Vitamin C-Assisted Synthesized Mn-Co Oxides with Improved Oxygen Vacancy Concentration: Boosting Lattice Oxygen Activity for the Air-Oxidation of 5-(Hydroxymethyl)furfural

Huai Liu et al.

Summary: This study successfully synthesized mesoporous Mn-Co spinel oxides with improved oxygen vacancy concentration using a vitamin C-assisted method, which showed high FDCA yield. Experimental and density functional theory calculations demonstrated that increasing oxygen vacancy concentration enhances oxidant activation rate and substrate adsorption capability.

ACS CATALYSIS (2021)

Review Chemistry, Physical

Recent Advances in Catalytic Conversion of Biomass to 2,5-Furandicarboxylic Acid

Hanyu Cong et al.

Summary: The conversion of biomass into high value-added compounds is gaining attention for addressing fossil fuel consumption and global warming. 5-Hydroxymethylfurfural (HMF) is a versatile biomass-derived building block used for synthesizing sustainable fuels and chemicals, with 2,5-furandicarboxylic acid (FDCA) being a desirable alternative for biodegradable polyesters.

CATALYSTS (2021)

Review Chemistry, Multidisciplinary

Sustainable production of pharmaceutical, nutraceutical and bioactive compounds from biomass and waste

Claudia Espro et al.

Summary: This tutorial review provides a general overview of processes, technologies, and challenges in producing pharmaceutical and bioactive compounds from food waste and lignocellulosic residues, with a focus on environmentally sustainable processes and novel green synthetic routes. Recent successful industrial applications of using food waste and lignocellulosic residues for pharmaceutical and nutraceutical purposes are also discussed.

CHEMICAL SOCIETY REVIEWS (2021)

Review Chemistry, Multidisciplinary

Recent advances in metal-free heteroatom-doped carbon heterogonous catalysts

Yalda Rangraz et al.

Summary: Heteroatom-doped carbon materials have gained attention as effective heterogeneous catalysts to replace metal-based catalysts due to their excellent physicochemical properties and structure characteristics. Doping of heteroatoms can tailor the properties of carbons for different utilizations, resulting in superior catalytic activity compared to pure carbon catalysts in many organic reactions.

RSC ADVANCES (2021)

Review Chemistry, Multidisciplinary

Electrochemical oxidation of biomass derived 5-hydroxymethylfurfural (HMF): pathway, mechanism, catalysts and coupling reactions

Yuechao Yang et al.

Summary: Electrochemical conversion is becoming a powerful and promising method for producing high-value chemicals, particularly the electrooxidation of HMF to FDCA which may replace petroleum-based PET. This review discusses the reaction pathway/mechanism, catalysts, and coupling reactions of HMF electrochemical oxidation, providing insights for utilizing and producing renewable resources.

GREEN CHEMISTRY (2021)

Article Chemistry, Physical

Ni/NiO heterostructures encapsulated in oxygen-doped graphene as multifunctional electrocatalysts for the HER, UOR and HMF oxidation reaction

Jianmin Wang et al.

Summary: By encapsulating nickel/nickel oxide nanoparticles in graphene and introducing oxygen doping through a post-annealing process, the prepared Ni/NiO@graphene catalysts exhibit superior activity for both water splitting and urea oxidation reactions, providing a potential strategy for addressing energy challenges.

CATALYSIS SCIENCE & TECHNOLOGY (2021)

Review Chemistry, Multidisciplinary

Production of HMF, FDCA and their derived products: a review of life cycle assessment (LCA) and techno-economic analysis (TEA) studies

Matthew G. Davidson et al.

Summary: Research suggests that bio-based production of HMF and FDCA may reduce CO2 emissions compared to fossil-based products, but it can also increase environmental impacts in other categories, with expensive feedstocks and high energy demands making it less economically viable. Further investigation into different raw materials, energy production methods, and catalytic systems may help improve the production of HMF and FDCA.

GREEN CHEMISTRY (2021)

Article Chemistry, Applied

Straightforward synthesis of beta zeolite encapsulated Pt nanoparticles for the transformation of 5-hydroxymethyl furfural into 2,5-furandicarboxylic acid

Xiaoling Liu et al.

Summary: This study successfully synthesized beta zeolite-encapsulated Pt nanoparticles (Pt@Beta) using an unusual acid hydrolysis preaging step, demonstrating high catalytic activity and stability in the transformation reaction. The research provides a new approach for the application of noble metal nanoparticles in catalysis.

CHINESE JOURNAL OF CATALYSIS (2021)

Article Chemistry, Multidisciplinary

From sugars to FDCA: a techno-economic assessment using a design concept based on solvent selection and carbon dioxide emissions

Amir Al Ghatta et al.

Summary: The production of 2,5-furandicarboxylic acid (FDCA) from sugars for the replacement of PET by PEF faces challenges related to the stability and isolation of the precursor HMF. Different solvents have varying impacts on cost, emissions, and commercial viability. A two-step, one-pot reaction is shown to be an economically and environmentally feasible solution, making FDCA competitive with terephthalic acid. Further research is needed to optimize the process and reduce emissions.

GREEN CHEMISTRY (2021)

Article Chemistry, Physical

A CuMn2O4 spinel oxide as a superior catalyst for the aerobic oxidation of 5-hydroxymethylfurfural toward 2,5-furandicarboxylic acid in aqueous solvent

Xiaoyue Wan et al.

Summary: A CuMn2O4 spinel oxide prepared via a freezing-assisted sol-gel method was used as a catalyst for the aerobic oxidation of 5-hydroxylmethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA) in aqueous solvent, achieving a high FDCA yield. Kinetic studies showed the primary reaction route and the rate-determining step over the CuMn2O4 spinel. Characterization measurements indicated that the enrichment of Mn species and appropriate metal ratios on the catalyst surface facilitated oxygen mobility and enhanced FDCA formation through synergistic effects between Mn and Cu.

CATALYSIS SCIENCE & TECHNOLOGY (2021)

Article Chemistry, Physical

Effect of Gold Particles Size over Au/C Catalyst Selectivity in HMF Oxidation Reaction

Cristina Megias-Sayago et al.

CHEMCATCHEM (2020)

Review Biotechnology & Applied Microbiology

Biocatalytic production of 2,5-furandicarboxylic acid: recent advances and future perspectives

Haibo Yuan et al.

APPLIED MICROBIOLOGY AND BIOTECHNOLOGY (2020)

Article Biochemistry & Molecular Biology

Sequential oxidation of 5-hydroxymethylfurfural to furan-2,5-dicarboxylic acid by an evolved aryl-alcohol oxidase

Javier Vina-Gonzalez et al.

BIOCHIMICA ET BIOPHYSICA ACTA-PROTEINS AND PROTEOMICS (2020)

Article Chemistry, Physical

Synergistic chemo/biocatalytic synthesis of 2,5-furandicarboxylic acid from 5-hydroxymethylfurfural

Zi-Yue Yang et al.

CATALYSIS COMMUNICATIONS (2020)

Article Chemistry, Multidisciplinary

Faceted Branched Nickel Nanoparticles with Tunable Branch Length for High-Activity Electrocatalytic Oxidation of Biomass

Agus R. Poerwoprajitno et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

Microwave-Assisted Oxidation of Hydroxymethyl Furfural to Added-Value Compounds over a Ruthenium-Based Catalyst

Deyang Zhao et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2020)

Article Chemistry, Multidisciplinary

Aerobic Oxidation of 5-Hydroxymethylfurfural into 2,5-Furandicarboxylic Acid over Gold Stabilized on Zirconia-Based Supports

Abdallah I. M. Rabee et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2020)

Article Nanoscience & Nanotechnology

Template-Free Synthesis of Mesoporous β-MnO2 Nanoparticles: Structure, Formation Mechanism, and Catalytic Properties

Yui Yamaguchi et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

Article Chemistry, Multidisciplinary

Identifying the Geometric Site Dependence of Spinel Oxides for the Electrooxidation of 5-Hydroxymethylfurfural

Yuxuan Lu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Biotechnology & Applied Microbiology

Screening and Evaluation of New Hydroxymethylfurfural Oxidases for Furandicarboxylic Acid Production

Mario Vinambres et al.

APPLIED AND ENVIRONMENTAL MICROBIOLOGY (2020)

Review Chemistry, Multidisciplinary

A Perspective on PEF Synthesis, Properties, and End-Life

Katja Loos et al.

FRONTIERS IN CHEMISTRY (2020)

Review Chemistry, Physical

Status of Biocatalysis in the Production of 2,5-Furandicarboxylic Acid

Derek Troiano et al.

ACS CATALYSIS (2020)

Article Green & Sustainable Science & Technology

Electrocatalytic Oxidation of 5-Hydroxymethylfurfural into the Monomer 2,5-Furandicarboxylic Acid using Mesostructured Nickel Oxide

Fabian Joschka Holzhaeuser et al.

ADVANCED SUSTAINABLE SYSTEMS (2020)

Article Chemistry, Inorganic & Nuclear

Influence of Carbon Supports on Palladium Nanoparticle Activity toward Hydrodeoxygenation and Aerobic Oxidation in Biomass Transformations

Juan C. Espinosa et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2019)

Article Chemistry, Multidisciplinary

Toward Sustainable Phenolic Thermosets with High Thermal Performances

Lerys Granado et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Article Chemistry, Multidisciplinary

Continuous-Flow Oxidation of HMF to FDCA by Resin-Supported Platinum Catalysts in Neat Water

Francesca Liguori et al.

CHEMSUSCHEM (2019)

Review Chemistry, Multidisciplinary

When Will 5-Hydroxymethylfurfural, the Sleeping Giant of Sustainable Chemistry, Awaken?

Konstantin Galkin et al.

CHEMSUSCHEM (2019)

Article Agricultural Engineering

Biotransformation of 5-hydroxymethylfurfural by Acinetobacter oleivorans S27 for the synthesis of furan derivatives

Tharangattumana Krishnan Godan et al.

BIORESOURCE TECHNOLOGY (2019)

Review Engineering, Chemical

Clean Catalytic Oxidation for Derivatization of Key Biobased Platform Chemicals: Ethanol, Glycerol, and Hydroxymethyl Furfural

Maria Alejandra Ayude et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2019)

Article Biotechnology & Applied Microbiology

Complete oxidation of hydroxymethylfurfural to furandicarboxylic acid by aryl-alcohol oxidase

Ana Serrano et al.

BIOTECHNOLOGY FOR BIOFUELS (2019)

Article Engineering, Chemical

Catalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic acid over Ru/Al2O3 in a Trickle-Bed Reactor

Anna Danielli da Fonseca Ferreira et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2019)

Article Chemistry, Multidisciplinary

Effect of MnO2 Crystal Structure on Aerobic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid

Eri Hayashi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Multidisciplinary

Carbon Support with Tunable Porosity Prepared by Carbonizing Chitosan for Catalytic Oxidation of 5-Hydroxylmethylfurfural

Hyejin Yu et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Article Chemistry, Multidisciplinary

Convergent production of 2,5-furandicarboxylic acid from biomass and CO2

Hua Zhou et al.

GREEN CHEMISTRY (2019)

Article Chemistry, Multidisciplinary

AuPd-nNiO as an effective catalyst for the base-free oxidation of HMF under mild reaction conditions

Danao Bonincontro et al.

GREEN CHEMISTRY (2019)

Article Biotechnology & Applied Microbiology

Isolation of 5-hydroxymethylfurfural biotransforming bacteria to produce 2,5-furan dicarboxylic acid in algal acid hydrolysate

Chu-Fang Yang et al.

JOURNAL OF BIOSCIENCE AND BIOENGINEERING (2018)

Article Green & Sustainable Science & Technology

Life cycle assessment of photodegradable polymeric material derived from renewable bioresources

Claudia Isola et al.

JOURNAL OF CLEANER PRODUCTION (2017)

Article Chemistry, Multidisciplinary

Visible-Light-Driven Valorization of Biomass Intermediates Integrated with H2 Production Catalyzed by Ultrathin Ni/CdS Nanosheets

Guanqun Han et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Engineering, Environmental

Base-free conversion of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid in ionic liquids

Dongxia Yan et al.

CHEMICAL ENGINEERING JOURNAL (2017)

Review Biochemical Research Methods

Recent advances in whole cell biocatalysis techniques bridging from investigative to industrial scale

Jochen Wachtmeister et al.

CURRENT OPINION IN BIOTECHNOLOGY (2016)

Article Chemistry, Multidisciplinary

Combined biomass valorization and hydrogen production in a photoelectrochemical cell

Hyun Gil Cha et al.

NATURE CHEMISTRY (2015)

Review Chemistry, Physical

Preparative Biotransformations: Oxidation of Alcohols

Diego Romano et al.

CHEMCATCHEM (2012)

Article Chemistry, Applied

Production of Oxidized Derivatives of 5-Hydroxymethylfurfural (HMF)

Michael A. Lilga et al.

TOPICS IN CATALYSIS (2010)