4.8 Review

What is Next in Anion-Exchange Membrane Water Electrolyzers? Bottlenecks, Benefits, and Future

Journal

CHEMSUSCHEM
Volume 15, Issue 8, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.202200027

Keywords

anion-exchange membrane; electrocatalysis; electrolyzers; platinum-group metal-free; water electrolysis

Funding

  1. Italian Ministry of Education, Universities and Research (Ministero dell'Istruzione, dell'Universita e della Ricerca - MIUR) through the Rita Levi Montalcini 2018 fellowship [PGR18MAZLI]
  2. Italian Ministry of University and Research (MIUR) through grant Dipartimenti di Eccellenza - 2017 - Materials for energy
  3. Italian ministry MIUR [FISR2019_01294]
  4. European Union [881603, 721065]
  5. Nancy & Stephen Grand Technion Energy Program (GTEP)
  6. French-Israeli Joint Research Project [PRC 2019-2021, PRC2347, 3-15578]
  7. Universita degli Studi di Milano-Bicocca within the CRUI-CARE Agreement

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This article discusses the development status of anion-exchange membrane water electrolyzers (AEM-WE) and highlights the key aspects for research and potential routes for overcoming the remaining issues.
As highlighted by the recent roadmaps from the European Union and the United States, water electrolysis is the most valuable high-intensity technology for producing green hydrogen. Currently, two commercial low-temperature water electrolyzer technologies exist: alkaline water electrolyzer (A-WE) and proton-exchange membrane water electrolyzer (PEM-WE). However, both have major drawbacks. A-WE shows low productivity and efficiency, while PEM-WE uses a significant amount of critical raw materials. Lately, the use of anion-exchange membrane water electrolyzers (AEM-WE) has been proposed to overcome the limitations of the current commercial systems. AEM-WE could become the cornerstone to achieve an intense, safe, and resilient green hydrogen production to fulfill the hydrogen targets to achieve the 2050 decarbonization goals. Here, the status of AEM-WE development is discussed, with a focus on the most critical aspects for research and highlighting the potential routes for overcoming the remaining issues. The Review closes with the future perspective on the AEM-WE research indicating the targets to be achieved.

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