Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 17, Issue 13, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.202200141
Keywords
Main group elements; Germanium; Germylene; Digermylene; Nucleophilic addition
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Funding
- National Natural Science Foundation of China [21771194]
- DFG [RO 224/70-1]
- Projekt DEAL
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A series of novel digermylene compounds were synthesized and used as important building blocks in organic synthesis. Various substituted digermylenes were obtained by reacting different ligands, and their structures were characterized using various analytical techniques.
A series of digermylenes R(EGeL)(2) (L=CH[C(Me)N(Ar)](2), Ar=2,6-iPr(2)C(6)H(3); E=O, R=1,3-C6H4 (1), 1,4-C6H4 (2), Me2C(CH2)(2) (3); E=NH, R=1,4-C6H4 (4), 1,4-C6H10 (5); E=C(O)O, R=1,3-C6H4 (6)) were synthesized by the reactions of L ' Ge (L '=HC[C(CH2)N(Ar)]C(Me)N(Ar), Ar=2,6-iPr(2)C(6)H(3)) with selected diphenols, diol, diamines, and o-/m-phthalic acids, respectively. Treatment of digermylene 1,3-C6H4(OGeL)(2) (1) with sulfur, selenium and CuX (X=Cl, Br, I) led to the formation of 1,3-C6H4[OGe(S)L](2) (8), 1,3-C6H4[OGe(Se)L](2) (9), and (CuX)(2)[1,3-C6H4(OGeL)(2)](2) (X=Cl (10), Br (11), I (12)), respectively. The obtained products were characterized by melting point, elemental analysis, FT-IR, H-1 and C-13 NMR spectroscopy, and single-crystal X-ray diffraction.
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