4.6 Article

Coalescence time of water-in-oil emulsions under shear

Journal

CHEMICAL ENGINEERING SCIENCE
Volume 250, Issue -, Pages -

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ces.2021.117257

Keywords

Coalescence time; Water-in-oil; Microfluidics; Shear flow

Funding

  1. Saudi Aramco [1958]
  2. KAUST: ORS

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In this study, microfluidic techniques were used to investigate the coalescence dynamics of water-in-oil emulsions in a simple shear flow. Experimental results showed a strong correlation between the coalescence time and the droplet approach velocity, effective diameter, offset, and continuous-phase viscosity. A scaling law for the dimensionless time needed for coalescence was also revealed.
Here we use microfluidic techniques to study the coalescence dynamics of water-in-oil emulsions in a simple shear flow. Single water-in-oil emulsion droplets are produced in a glass-capillary-based emulsion generator under Rayleigh-Plateau instability. This droplet is guided into a collision channel, inside which it shears past a stationary water droplet held by surface tension at a nozzle protruding through the wall. Two high-speed cameras with perpendicular views track the droplet interactions. Over 2,000 trajectories were recorded to investigate the interaction time needed for coalescence of the two drops. We study the dependence of this coalescence time t(c) on droplet approach velocity V, effective diameter D-H, offset delta(x) and continuous-phase viscosity. We find that t(c) (similar to)& nbsp;V-1, indicating strong correlation between coalescence time and Vin our 3-D system, in contrast to results reported from two-dimensional micro-fluidic collision channels. Finally, the experimental results reveal scaling law for dimensionless time needed for coales-cence as t(c & nbsp;similar to)& nbsp;D-H delta x-V-0:5(-1), when the channel confinement effects are minimal.(C)& nbsp;2021 Elsevier Ltd. All rights reserved.

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