Journal
CHEMCATCHEM
Volume 14, Issue 11, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.202200126
Keywords
Asymmetric isomerization; Allylic alcohols; Organocatalysis; Tandem reaction; Transition-metal catalysis
Categories
Funding
- National Key Research and Development Program of China [2021YFC2102400]
- Shanghai Science and Technology Innovation Action Plan [21N41900500, 20JC1416900]
- National Natural Science Foundation of China [22171087]
- Fundamental Research Funds for the Central Universities
- open foundation of Key Laboratory of Tropical Medicinal Resource Chemistry of Ministry of Education [rdzh2020003]
- Zijiang Scholar Program of ECNU
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This minireview summarizes the recent advancements in catalytic enantioselective isomerization and tandem reactions, discusses their advantages and limitations, and highlights the synthetic opportunities for further development.
Catalytic asymmetric isomerization of allylic or homoallylic alcohols into synthetically useful carbonyl compounds is a redox-neutral and 100 % atom-economic transformation, which is of great interest and has gained increasing attention from both academic and industry. This minireview summarizes the advances in catalytic enantioselective isomerization and it involved tandem reactions over the past five years, also discusses their advantages and limitations, and expounds the synthetic chances still open for further development.
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