Journal
CHEMCATCHEM
Volume 14, Issue 14, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.202200254
Keywords
basicity; Cu2O; tantalate; preferential adsorption; hydrogenation of 3-Nitrostyrene; selectivity
Categories
Funding
- National Natural Science Foundation of China [22062016, 21861029]
- Major Project of Inner Mongolia Natural Science Foundation [2020ZD02]
- Project of Inner Mongolia Research and Development of Applied Technology [2020SGG0065]
- Project of Grassland Talent Innovation Team [12000-12102619]
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The selective hydrogenation of nitroarenes has wide application in industrial production. Combining Cu2O and tantalate catalysts can increase the activity and selectivity. The activity and selectivity are related to the catalysts' intrinsic basicity and the preferential adsorption toward functional groups.
The selective hydrogenation of nitroarenes bearing competitive reducible groups to produce functionalized amino compounds has wide application in industrial production. However, to control only reducing the target group is still a challenge. Here, Cu2O/M2Ta2O6 (M=H, Li, Na, K, Ag, Bi) catalysts were prepared to evaluate their catalytic performance using 3-nitrostyrene (3-NS) as a model reaction. The results confirm pristine Cu2O has a highly activity to hydrogenate 3-NS but low selectivity with the coexisted products of 3-vinylaniline (3-VA), 3-ethylaniline(3-EA) and 1-ethyl-3-nitrobenzene (3-NE), whereas the independent tantalate can converse 3-NS to sole product 3-VA via absolutely preferential reduction of -NO2 moiety but with a low conversion rate. Importantly, if combining Cu2O and tantalate, the activity and selectivity of the appointed product were all obviously increased. Furthermore, the hydrogenation activity of 3-NS to generate 3-VA is positively related with the catalysts' intrinsic basicity and the preferential adsorption toward -NO2 group.
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