4.7 Article

Laser damage resistance of plasma-sprayed alumina and honeycomb skeleton/alumina composite ceramic coatings

Journal

CERAMICS INTERNATIONAL
Volume 48, Issue 6, Pages 7885-7896

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2021.11.336

Keywords

Honeycomb skeleton; Composite coating; Laser damage resistance; Crack; Thermal conductivity

Funding

  1. National Natural Science Foundation of China [51475238]
  2. Key Research and Development Program of Jiangsu Provincial Department of Science and Technology of China [BE2019002]
  3. China Post Doctoral Fund [2020M671475]

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By studying Al2O3 and honeycomb skeleton-Al2O3 composite coatings, it was found that the honeycomb skeleton improved the thermal conductivity and thermal diffusivity of the coatings, and had a smaller impact on crack propagation.
Al2O3 and honeycomb skeleton-Al2O3 composite coatings on Titanium alloy (Ti-6Al-4V) were prepared by atmospheric plasma spraying. A laser ablation experiment on as-sprayed coatings was performed. In this paper, the laser damage resistance, microstructure, phase composition of Al2O3 coatings were examined. 3D Dimensional Confocal Microscopy, Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), and Energy Dispersive Spectrometry (EDS) characterized the laser damage morphology, microstructure, phase composition, and element analysis, respectively. The influence of the honeycomb skeleton on the laser ablation damage on assprayed coatings was investigated by a comparative analysis of the laser damage morphology with different laser ablation times and gas flow. The results show that the honeycomb skeleton raises thermal conductivity and thermal diffusivity. Moreover, a tower-like dendrite was generated during the laser irradiation of the composite coating. The honeycomb skeleton refined the structure, suppressed crack propagation, and reduced the influence of gas flow on cracks. Under the same experimental laser ablation parameters, the laser damage area of the honeycomb skeleton-Al2O3 composite coating was smaller than that of the Al2O3 coating. It was demonstrated that the laser damage resistance of the honeycomb skeleton-Al2O3 composite coating was superior to that of the Al2O3 coating.

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