4.7 Article

A highly efficient Cu-ZnO/SBA-15 catalyst for CO2 hydrogenation to CO under atmospheric pressure

Journal

CATALYSIS TODAY
Volume 402, Issue -, Pages 60-66

Publisher

ELSEVIER
DOI: 10.1016/j.cattod.2022.03.002

Keywords

Copper catalyst; Dispersion; CO2 hydrogenation; Reverse water-gas shift

Funding

  1. National Natural Science Foundation of China
  2. [21878048]

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The conversion of CO2 to CO using Cu-ZnO/SBA-15 catalyst showed better catalytic performance and higher conversion rate compared to Cu/SBA-15 catalyst.
The conversion of CO2 to useful chemicals has been considered as an essential strategy to mitigate greenhouse gas emission. In this work, Cu/SBA-15 and Cu-ZnO/SBA-15 catalysts were prepared and used for CO2 hydro-genation to CO. Although both catalysts give excellent CO selectivity (99.9%), Cu-ZnO/SBA-15 exhibits more superior catalytic activity with CO2 conversion of 29.1% at400 degrees C and atmospheric pressure. High specific surface area and confinement structure of SBA-15 and the addition of ZnO make Cu nanoparticles more dispersed. Because of this extraordinary dispersion, Cu-ZnO/SBA-15 has strong ability to interact with CO2 and H2 and behaves better catalytic CO2 hydrogenation performance than most catalysts in previous articles. Moreover, Cu-ZnO/SBA-15 has good catalytic stability and has, therefore, great potential for industrial application.

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