4.6 Article

Stable and efficient hydrogen evolution reaction catalyzed by NiO-Rh2P heterostructure electrocatalyst

Journal

CATALYSIS COMMUNICATIONS
Volume 163, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.catcom.2022.106404

Keywords

Water splitting; Hydrogen evolution reaction; Heterostructure; Water dissociation

Funding

  1. National Natural Science Foundation of China [21703212]
  2. Zhejiang Provincial Natural Science Foundation of China [LGG21B030004]

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A NiO-Rh2P heterostructure electrocatalyst was constructed by phosphating NiO-Rh structure. It showed high water dissociation capability and lower overpotential, and exhibited robust stability due to the strong electronic interplay between NiO and Rh2P.
A NiO-Rh2P heterostructure electrocatalyst was constructed by phosphating the NiO-Rh structure. Due to the high capability of water dissociation by NiO, only 46 mV overpotential was demanded to achieve 10 mA cm(-2) for the NiO-Rh2P, which is 73 mV lower than Rh2P in alkaline HER catalysis. Besides, the strong electronic interplay between NiO and Rh2P also contributed to the robust stability of NiO-Rh2P heterostructure electrocatalyst.

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