Journal
CARBON
Volume 190, Issue -, Pages 57-67Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2021.12.097
Keywords
Graphene nanoscrolls; Microwave-assisted synthesis; Layered double hydroxide; Supercapacitor
Funding
- National Natural Science Foundation of China [22075044]
- Natural Science Foundation of Fujian Province [2020J01146]
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To enhance the electrochemical performance of electrode materials for energy storage devices, a core-shell heterostructure graphene nanoscrolls composite was designed and synthesized. This composite provides more active sites for pseudocapacitive reactions, promotes the collection/transport of electrons and ions, and buffers the volume variation of active matters during cycling. The as-obtained electrode exhibits a high specific capacitance and a long cycle life.
To enhance the electrochemical performance of electrode materials for energy storage devices, utilization the synergistic effect of EDLC-capacitance and pseudocapacitance as well as modification nanostructures are general strategies. Herein, we report the design and synthesis of an array core-shell heterostructure graphene nanoscrolls composite, in which petal-like NiCo-LDH nanoflakes are vertically anchored on the 3D interconnected GNSs skeleton, accomplished by a highly facile microwave-assisted method. This design combines several advantages, including providing more active sites for pseudocapacitive reactions, promoting the collection/transport of electrons and ions, and buffering the volume variation of active matters during cycling. Benefiting from the advantageous nanostructure, the asobtained NiCo-LDH@GNSs electrode exhibits a high specific capacitance of 1470 F g-1 at a current density of 1 A g-1 and a long cycle life with 81.6% retention after 1000 cycles. (c) 2022 Elsevier Ltd. All rights reserved.
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