The relationship between linear chain length distributions of amylopectin and the functional properties of the debranched starch-based films

The relationship between linear chain length distributions and the functional properties of the starch-based films after pullulanase debranching treatment of corn (CS), rice (RS) and wheat (WS) were investigated. The results indicated that the film thickness was negatively correlated with A chains content (r = -0.939) and apparent amylose content (r = -0.926), and was positively correlated with B3 chains content (r = 0.847). The tensile strength of the debranched starch-based films were positively correlated with apparent amylose content (r = 0.813), and the elongation at break were inversely proportional to B3 chains content (r = -0.817). The hydrophobicity of the starch-based films was positively and negatively correlated with the proportions of linear chains with DP 6-12 (r = 0.892) and DP 25-36 (r = -0.863), respectively. On the contrary, no significant correlation was noticed between chain length distribution of amylopectin and transparency and thermal stability.

Automated summary

The study revealed a close relationship between film thickness and chain length distributions, with tensile strength positively correlated with apparent amylose content and elongation at break inversely proportional to B3 chain content. Additionally, the hydrophobicity of the starch-based films was influenced by the proportions of DP 6-12 and DP 25-36 chains.