Journal
ISRAEL JOURNAL OF CHEMISTRY
Volume 56, Issue 6-7, Pages 454-462Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ijch.201500093
Keywords
carbocycles; heterocycles; Lewis acids; small ring systems; synthetic methods
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Funding
- Science and Engineering Research Board (SERB)
- Department of Science and Technology (DST)
- Council of Scientific and Industrial Research (CSIR), India
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The synthetic applications of aroyl- and nitro-substituted D-A cyclopropanes probed in the authors' laboratory are reviewed. These cyclopropanes, though looking similar, exhibit markedly different reactivity patterns. Lewis acid-mediated transformations of these cyclopropanes (in the presence or absence of a reaction partner) afford a variety of carbocycles and heterocycles. Mechanistic aspects of the reactions are discussed for clear understanding of the transformations.
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