4.7 Article

Enhanced photocatalytic performance of Ag/CdS by L-cysteine functionalization: Combination of introduced co-catalytic groups and optimized injection of hot electrons

Journal

APPLIED SURFACE SCIENCE
Volume 579, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.apsusc.2021.151838

Keywords

Surface plasmonic resonance; CdS nanosheets; Bridging ligands; L-Cys functionalization; Injection rate of hot electrons

Funding

  1. HIT (WH) -Weihai Co-construction Project [ITGAZMZ001 702]
  2. Natural Science Foundation of Shandong Province [ZR2020MA083]
  3. National Natural Science Foundation of China [11674146]

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In this study, the photocatalytic performance of CdS was enhanced by pre-functionalizing CdS nanosheets with L-cysteine (L-Cys) to graft -COO- and -NH2 groups, followed by photo-deposition of Ag nanoparticles. The optimal hydrogen evolution rate and monochromatic apparent quantum efficiency were significantly improved, with L-Cys serving as bridging ligands to enhance the injection rate of hot electrons and the -COO- and -NH2 groups on CdS functioning as efficient co-catalytic centers.
Surface plasmonic resonance effect of Ag nanoparticles (NPs) can enhance the photocatalytic performance of CdS by the injection rate of hot electrons, but their low injection rate and serious carrier recombination of CdS need special attention. In this article, CdS nanosheets are pre-functionalized by L-cysteine (L-Cys) to graft -COO- and -NH2 groups, followed by the photo-deposition of Ag NPs, and strong chemical bonds are formed between CdS and Ag NPs with L-Cys as bridging ligands. Their optimal hydrogen evolution rate of 29.71 mmol/g/h is 4.13 and 2.30 times that of CdS and CdS-Ag without L-Cys, respectively, and its monochromatic apparent quantum efficiency at 450 nm reaches 27.87%. According to the enhancement factors of L-Cys functionalization, L-Cys acts as bridging ligands to enhance the interfacial injection rate of hot electrons. Meanwhile, the dangling -COO- and -NH2 groups on CdS can act as efficient co-catalytic centers.

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