Journal
APPLIED CATALYSIS A-GENERAL
Volume 636, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.apcata.2022.118596
Keywords
TiO2; Oxygen defects; Hetero-phase junction; NH3; DFT calculation
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This study investigates the catalytic mechanism of electrocatalytic nitrate reduction to ammonia using TiO2 nano materials with hetero-phase junctions and oxygen defects. The oxygen defects are found to act as the adsorption sites of NO3-. Enhanced performance in NH3 synthesis is attributed to the strong interface interactions induced by Ti3+-Odef pairs and hetero-phase junctions. The reaction mechanism for NH3 synthesis from NO3- is revealed through online differential electrochemical mass spectrometry (DEMS) and density functional theory (DFT) calculations.
Electrocatalytic nitrate reduction to ammonia (NH3) has been received increasing attention due to the potential of both decontaminating nitrogen oxide (NOx) from industrial exhaust gas and providing an option for NH3 synthesis. However, their related catalytic process and mechanism dominated by the active phase structure and active sites of nitrate to ammonia electrocatalyst still remain unclear. To this end, in this study TiO2 nano materials with constructed hetero-phase junctions and oxygen defects were used to study the catalytic mechanism and make a clear of the function of hetero-phase junctions and defects. Combined with EPR and FT-IR methods, oxygen defects acted as the adsorption sites of NO3- are experimentally confirmed. Systematic characterizations further demonstrate that enhanced performance with the highest NH3 Faradaic efficiency (78.0%) and selectivity (81.9%) for NITRR can be attributed to the Ti3+- Odef pairs and hetero-phase junctions induced strong interface interactions between anatase and rutile phases. The online differential electrochemical mass spectrometry (DEMS) and density functional theory (DFT) calculations demonstrate that both Ti3+ Odef pairs and hetero-phase junctions lead to the decrease of adsorption energy of NO3- and promote the formation of *NOH intermediates, revealing the reaction mechanism for NH3 synthesis from NO3-.
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