4.8 Article

Towards Upcycling Biomass-Derived Crosslinked Polymers with Light

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 61, Issue 31, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202203353

Keywords

Biomass; Photodegradation; Phototriggered Materials; Polymer Degradation; Upcycling

Funding

  1. NSF [EPS IIA-1355466]
  2. Center for Sustainable Materials Science (CSMS)
  3. BGSU

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Photodegradable, recyclable, and renewable crosslinked polymers from bioresources have the potential to address the issue of plastics degradability and recyclability.
Photodegradable, recyclable, and renewable, crosslinked polymers from bioresources show promise towards developing a sustainable strategy to address the issue of plastics degradability and recyclability. Photo processes are not widely exploited for upcycling polymers in spite of the potential to have spatial and temporal control of the degradation in addition to being a green process. In this report we highlight a methodology in which biomass-derived crosslinked polymers can be programmed to degrade at approximate to 300 nm with approximate to 60 % recovery of the monomer. The recovered monomer was recycled back to the crosslinked polymer.

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