Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 61, Issue 31, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202205481
Keywords
CO2 Capture; Crystal-Rearrangement; Electrostatic-Induced Rearrangement; Porous Organic Cage
Categories
Funding
- National Key R&D Program of China [2021YFB3801301]
- National Natural Science Foundation of China [22075076, 21908054, 21908098]
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In this study, a crystal-rearrangement strategy induced by electrostatic attraction was used to design a POC membrane with heterostructure. The rearranged crystal layer, which was uniform and defect-free, displayed excellent CO2 separation performance and stability.
Porous Organic Cages (POCs) with tunable tailoring chemistry properties and polymer-like processing conditions are of great potential for molecular selective membranes, but it remains challenging in the assembly of high crystalline POCs with regular nanochannels for effective molecular sieving. Here we report an electrostatic-induced crystal-rearrangement strategy for the design of a POC membrane with heterostructure. Due to electrostatic attraction, ionic liquid molecules induced cage molecules to rearrange into a sub-10 nm uniform and defect-free crystal layer, which displayed competitive CO2 separation performance. The optimized hetero-structured membrane exhibited an attractive CO2/N-2 separation selectivity of over 130, which was superior to the state-of-the-art membranes, accompanied with excellent long-term and thermal shock stability. This strategy provides a new inspiration for the preparation of crystal-rearranged membranes with regular channels for gas molecule sieving.
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