Journal
IONICS
Volume 22, Issue 11, Pages 2169-2174Publisher
SPRINGER HEIDELBERG
DOI: 10.1007/s11581-016-1745-7
Keywords
ZnO; Sphere; Metal-organic precursor; Supercapacitor; Energy storage and conversion
Funding
- National Natural Science Foundation of China [51274130, 51074096]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT13026]
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In this paper, ZnO microspheres, which are composed of irregular nanoparticles, have been synthesized successfully from a metal-organic precursor. The average diameter is about 3.5 mu m and the specific surface area is 7.53 m(2) g(-1). Measured by electrochemical tests as electrode materials for supercapacitors, the ZnO powders show high specific capacitances (1017.5 Fg(-1) at 5 Ag-1 and 562.5 Fg(-1) at 50 Ag-1, respectively) and excellent cycling stability (the specific capacitance was kept at 631.2 Fg(-1) and 89.2 % retention after 3000 cycles at 18 Ag-1). These results show that the microspherical ZnO could be a potential electrode material for supercapacitors.
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