Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 364, Issue 8, Pages 1371-1387Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202200023
Keywords
Organofluorine compounds; 2-bromo-3,3,3-trifluoropropene (BTP); Transition metal catalyst
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Funding
- Zhejiang AF University [04251700031]
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In this review, we systematically summarize the applications of 2-bromo-3,3,3-trifluoropropene (BTP) in organic synthesis, including addition reactions, cross-coupling reactions, cycloaddition or cyclization reactions, S(N)2' reactions, and Stetter reactions, and discuss their mechanisms.
2-Bromo-3,3,3-trifluoropropene (BTP) represents a highly valuable synthon in synthetic chemistry, and has been widely used in organic synthesis, mainly including addition reactions, cross-coupling reactions, cycloaddition or cyclization reactions, S(N)2' reactions, and Stetter reactions for the construction of various fluorinated organic compounds. In this review, we systematically summarize these reactions; their mechanisms are also discussed.
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