Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 364, Issue 23, Pages 4152-4156Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202200184
Keywords
Ruthenium(II) catalysis; Hydroamination; Allenoates; Arylamines; E-allylic amines
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Funding
- National Natural Science Foundation of China [21702087, 21801105]
- LiaoNing Revitalization Talents Program [XLYC1907010, XLYC1902085]
- Research Project Fund of Liaoning Provincial Department of Education [L2020033, LJKZ0375]
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A ruthenium(II)-catalyzed hydroamination reaction of allenoates with arylamines has been developed, providing a straightforward and efficient approach to synthesize E-allylic amines with high selectivity and atom economy.
A ruthenium(II)-catalyzed hydroamination of allenoates with arylamines has been developed. This strategy provides an approach to synthesize E-allylic amines in good yields with high atom-economy and high levels of chemo-, regio- and E-selectivities with a broad substrate scope.
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