Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 364, Issue 7, Pages 1212-1222Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202200085
Keywords
Allene; Axial chirality; Enantioselectivity; Organocatalysis; Propargyl derivatives
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Funding
- Shenzhen Innovation of Science and Technology Commission [20200925151614002]
- Natural Science Foundation of Shandong Province [ZR2021MB026]
- Special Funds of the Taishan Scholar Program of Shandong Province [tsqn201812047]
- Guangdong Provincial Key Laboratory of Catalysis [2020B121201002]
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Axially chiral allenes are important natural products and synthetic molecules with significant biological activity. The catalytic enantioselective synthesis of these compounds has been widely studied, and many simple and efficient methods have been developed, thanks to the advancements in asymmetric organocatalysis.
Axially chiral allenes occur on a wide range of natural products and synthetic molecules with significant biological activity. Furthermore, they are versatile building blocks in organic synthesis because of their inherent chemical properties. Accordingly, catalytic enantioselective synthesis of axially chiral allenes has been paid much attention. Benefited from the development of asymmetric organocatalysis, many simple and efficient methods in terms of different catalytic systems as well as reaction partners have been developed. This review will focus on the recent progress in the field of organocatalytic enantioselective synthesis of allenes (2000-2022), which is organized according to types of allenes and the catalyst system used.
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