4.8 Article

Search for New Anode Materials for High Performance Li-Ion Batteries

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 14, Issue 18, Pages 20326-20348

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.1c25262

Keywords

Li-ion batteries; anodes; oxides; sulfides; carbides; metal-organic frameworks (MOFs); covalent-organic frameworks (COFs); hybrid perovskites

Funding

  1. TCG-CREST funding of the battery program at IISER Pune
  2. Global Research Translation Award (GRTA)

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Li-ion batteries are the highest performing rechargeable batteries, but traditional graphite anodes have limitations in meeting the increasing energy density requirements. Therefore, research on alternative anode materials is crucial. Additionally, the use of earth abundant materials for battery electrodes can reduce costs.
Owing to an unmatched combination of power and energy density along with cyclic stability, the Li-ion battery has qualified itself to be the highest performing rechargeable battery. Taking both transportable and stationary energy storage requirements into consideration, Li-ion batteries indeed stand tall in comparison to any other existing rechargeable battery technologies. However, graphite, which is still one of the best performing Li-ion anodes, has specific drawbacks in fulfilling the ever-increasing energy and power density requirements of the modern world. Therefore, further research on alternative anode materials is absolutely essential. Equally important is the search for and enhanced use of right earth abundant materials for battery electrodes so as to bring down the costs of the battery systems. In this spotlight article, we discuss the current research progress in the area of alternative anode materials for Li ion battery, putting our own research work over the past several years into perspective. Starting from conversion anode systems like oxides and sulfides, to insertion cum alloying systems like transition metal carbides, to molecularly engineered open framework systems like metal organic frameworks (MOFs), covalent organic frameworks (COFs), and organic-inorganic hybrid perovskites (OIHPs), this spotlight provides a complete essence of the recent developments in the area of alternative anodes. The possible and potential impact of these new anode materials is detailed and discussed here.

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