4.8 Article

Enhancing the Intrinsic and Extrinsic Stability of Halide Perovskite Nanocrystals for Efficient and Durable Optoelectronics

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 14, Issue 30, Pages 34291-34302

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.2c01822

Keywords

core-shell perovskite nanocrystals; encapsulation; MOF coating; metal oxide coating; polymer coating

Funding

  1. Spanish Ministerio de Ciencia e Innovacibn through Ram bn y Cajal grant [RYC2018-026103-I]
  2. Spanish State Research Agency [PID2020-117371RA-I00]
  3. Xunta de Galicia [ED431F2021/05]
  4. Universidade de Vigo/CISUG

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Metal halide perovskite nanocrystals have attracted attention in the research of colloidal semiconductor nanomaterials due to their properties and potential applications. However, their phase instability and chemical degradation hinder real-world applications. To address these issues, researchers have proposed strategies such as doping and encapsulation to enhance stability.
Over the past few years, metal halide perovskite nanocrystals have been at the forefront of colloidal semiconductor nanomaterial research because of their fascinating properties and potential applications. However, their intrinsic phase instability and chemical degradation under external exposures (high temperature, water, oxygen, and light) are currently limiting the real-world applications of perovskite optoelectronics. To overcome these stability issues, researchers have reported various strategies such as doping and encapsulation. The doping improves the optical and photoactive phase stability, whereas the encapsulation protects the perovskite NCs from external exposures. This perspective discusses the rationale of various strategies to enhance the stability of perovskite NCs and suggests possible future directions for the fabrication of optoelectronic devices with long-term stability while maintaining high efficiency.

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