4.8 Article

Pre-trimethylindium Flow Treatment of GaInN/GaN Quantum Wells to Suppress Surface Defect Incorporation and Improve Efficiency

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 14, Issue 22, Pages 26264-26270

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.2c05585

Keywords

III-nitride; metalorganic vapor phase epitaxy; pre-TMIn flow treatment; quantum wells; time-resolved photoluminescence; capacitance-voltage characteristics

Funding

  1. MEXT Private University Research Branding Project
  2. MEXT Program for research
  3. JSPS KAKENHI for Scientific Research A [15H02019, 17H01055]
  4. JSPS KAKENHI for Innovative Areas [16H06416]
  5. Japan Science and Technology CREST [16815710]

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This study aims to improve the emission efficiency of GaInN-based green LEDs using pre-TMIn flow treatment of quantum wells. The investigation shows that this treatment effectively deactivates and neutralizes surface defects, leading to improved emission intensity. Through the analysis of prepared samples, it is demonstrated that the pre-TMIn flow treatment of quantum wells effectively suppresses surface defect incorporation, thereby enhancing emission intensity.
This study aims to improve the emission efficiency of GaInN-based green light-emitting devices (LEDs) using the pre-trimethylindium (TMIn) flow treatment of a quantum well (QW) since we hypothesize that the pre-TMIn flow treatment is able to suppress the incorporation of surface defects (SDs) from the n-type GaN surface into the QWs. For this purpose, first, we investigate the effect of TMIn flow treatment on the SDs in n-type GaN samples by measuring time-resolved photoluminescence. The result of the investigation shows that the TMIn flow treatment effectively deactivated and/or neutralized the SDs from acting as the non-radiative recombination centers. Next, we prepare and investigate the GaInN-based green LEDs employing five pairs of multiple quantum wells (MQWs), in which the number of pre-TMIn treated QWs varies from zero to five. Through the analysis of prepared samples, we demonstrate that the pre-TMIn flow treatment of QWs works effectively in suppressing the SD incorporation into the MQWs, thereby improving the emission intensity.

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