4.1 Article

Lightweight aggregates produced by granulation of peat-wood fly ash with alkali activator

Journal

INTERNATIONAL JOURNAL OF MINERAL PROCESSING
Volume 149, Issue -, Pages 42-49

Publisher

ELSEVIER
DOI: 10.1016/j.minpro.2016.02.006

Keywords

Alkali activation; Geopolymer; Granulation; Agglomeration; Lightweight aggregate; Fly ash

Funding

  1. GEOPO project - Finnish Funding Agency for Technology and Innovation (Tekes)
  2. Boliden Harjavalta Oy
  3. Ekokem-Palvelu Oy
  4. Fortum Power and Heat Oy
  5. Helen Oy
  6. Jyvaskylan Energia Oy
  7. Kemira Chemicals Oy
  8. Valmet Power Oy
  9. Metsa Group
  10. Napapiirin Energia ja Vesi
  11. Stora Enso Oyj
  12. UPM
  13. Renlund Foundation

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This study presents a new method to produce lightweight aggregates (LWAs) by granulating peat-wood ash using alkali activators. Peat-wood ash was granulated with potassium silicate and sodium aluminate in a high shear granulator to produce spherical granules. Blast furnace slag, coal fly ash and metakaolin were studied as co-binders. A suitable liquid/solid ratio, granulation growth type, microstructure, strength, and crystal structure of granules have been determined. The granulation proceeded by induction-type growth behaviour and suitable liquid/solid ratio was between 0.34 and 0.43. In the BSE images it was observed that the precursor particles were embedded in a dense alumino-silicate matrix. The X-ray diffraction analysis supported the success of the alkali activation. All co-binders increased the strength of the granules, but the blast furnace slag produced the strongest granules. The study shows that by simultaneous granulation and alkali activation it is possible to increase the utilisation of ash and produce valuable products. (C) 2016 Elsevier B.V. All rights reserved.

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