Journal
ACS APPLIED POLYMER MATERIALS
Volume 3, Issue 11, Pages 5441-5451Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsapm.1c00769
Keywords
phase-change polymer; thermal energy storage; emulsion gel; cellulose nanofiber; stearyl methacrylate
Funding
- Kyoto University Nano Technology Hub in Nanotechnology Platform Project - Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan
- Japan Society for the Promotion of Science [P18395]
- JST-Mirai Program [JPMJMI18E3]
- JSPS [17H01480]
- Grants-in-Aid for Scientific Research [17H01480] Funding Source: KAKEN
- Austrian Science Fund (FWF) [P18395] Funding Source: Austrian Science Fund (FWF)
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The study developed a film-forming phase-change polymer synthesized from emulsion gels stabilized by cellulose nanofiber-based amphiphiles, achieving solid-solid phase transition with efficient energy storage performance. The composite film showed a high latent heat for melting and crystallization, providing significant advancement in designing efficient energy-storage materials using plant-derived biocompatible nanomaterials.
Phase-change polymers (PCPs), exhibiting solid-solid phase transition, bring advancement to the conventional solid-liquid system for thermal energy storage. Such a system obtained as an aqueous dispersion is recommended for application as a surface coating. However, achieving good colloidal stability with efficient energy-storage performance requires precise process designing. Herein, we developed a film-forming PCP that was synthesized from emulsion gels stabilized by cellulose nanofiber-based amphiphiles (CLAm's). The CLAm was obtained by grafting an amphiphile at a significantly higher degree (0.2-2.4). Depending on the degree of substitution and type of oil, the CLAm was able to efficiently stabilize o/w emulsion gels containing a very high oil phase (>90.0%) at a concentration of about 0.1 wt %. The PCPs were produced by the copolymerization of stearyl methacrylate (SMA) and methyl methacrylate used as the oil phase in emulsion gels. The composite film obtained from the colloidal dispersion of P(SMA-co-MMA) exhibited a solid-solid (crystalline-amorphous) phase transition involving high latent heat of upto similar to 98 J/g for the melting and crystallization of SMA segments at similar to 35 and similar to 25 degrees C, respectively. This approach provides significant advancement in designing an efficient energy-storage material using plant-derived biocompatible nanomaterials.
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