4.7 Article

Influence of Topical Cross-Linking on Mechanical and Ballistic Performance of a Woven Ultra-High-Molecular-Weight Polyethylene Fabric Used in Soft Body Armor

Journal

ACS APPLIED POLYMER MATERIALS
Volume 3, Issue 11, Pages 6008-6018

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsapm.1c01301

Keywords

cross-linking; diazirines; UHMWPE; mechanical properties; ballistic tests

Funding

  1. Mitacs Canada [IT11982]
  2. Innovation for Defence Excellence and Security (IDEaS) Program of the Canadian Department of National Defence [CFPMN1-026-UBC]
  3. Canada Research Chairs program [950231376]

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Topical cross-linking of UHMWPE fabric can enhance its resistance to tear and perforation, potentially increasing the protection provided by soft body armor. The cross-linking strengthens the fabric, particularly along its bias direction. Experiments show that even with just 1% cross-linker, the ballistic limit can be significantly increased by 18 m/s.
We demonstrate that topical cross-linking of woven ultra-high molecular weight polyethylene (UHMWPE) fabric with a small-molecule bis-diazirine reagent can enhance the fabric's resistance to tear and perforation and could provide a lead to further increase the protection provided by a soft body armor made from UHMWPE materials. A series of experiments confirms that the enhancement is likely due to cross-links formed within and between the yarns constituting the woven fabric and that cross-linking particularly strengthens the fabric along its bias direction. The treated fabric was incorporated into multilayer composite panels and challenged in ballistic tests. These measurements revealed that as low as a 1 wt % cross-linker can significantly increase the V-50 ballistic limit by 18 m/s.

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