Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 41, Issue 47, Pages 22009-22016Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2016.08.133
Keywords
Molybdenum nitride; Cocatalyst; Photocatalysis; H-2 evolution
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Funding
- National Natural Science Foundation of China (NSFC) [21263018]
- Project of Science and Technology of Personnel of Study Abroad [NingXia (2014) 486]
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Mo2N as an efficient non-noble metal cocatalyst was firstly reported for improving photocatalytic H-2 evolution under visible light irradiation. The activity of 2.0% Mo2N/CdS is 6.1 times of CdS alone and 1.4 times of 1.0% Pt/CdS. The longevity test shows the Mo2N/CdS is very stable in 42 h. After 42 h, the activity of Mo2N/CdS gradually decreases. However, even after 90 h, the activity of Mo2N/CdS also keeps the 49% of that fresh catalyst. The molybdenum oxides, CdMoO4 on the surface of Mo2N may combine CdS with Mo2N closely, protect Mo2N cocatalyst and inhibit the reversible reaction of H-2 production, thus increase the photocatalytic activity and the stability of Mo2N/CdS. This study demonstrates Mo2N is a new efficient low cost non-noble metal cocatalyst in photocatalytic H-2 evolution. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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