Journal
CHEMPHOTOCHEM
Volume 6, Issue 5, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cptc.202200030
Keywords
coordination polymers; thiolate ligands; photoluminescence; NIR emission
Categories
Funding
- French National Agency (MEMOL project) [ANR-16-JTIC-0004-01]
- Rhone-Alpes region
- European Regional Development Fund [CZ.02.1.01/0.0/0.0/16_019/0000766]
- European Commission [101031503]
- Marie Curie Actions (MSCA) [101031503] Funding Source: Marie Curie Actions (MSCA)
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A series of d(10) coinage metal thiosalicylate coordination polymers (CPs) were reported, with 1D structures formed by M3S3 fused hexagons for Cu and Ag compounds and interpenetrated helical chains for Au CP. Depending on the metal, solid-state red and NIR emissive CPs were obtained with quantum yields up to 50%, providing a great opportunity to replace actual emissive critical raw materials.
A series of d(10) coinage metal thiosalicylate coordination polymers (CPs) is reported. The 1D structures of the three CPs are formed by M3S3 fused hexagons for Cu and Ag compounds and interpenetrated helical chains for Au CP. Depending on the metal, solid-state red and NIR emissive CPs are obtained with quantum yields up to 50 %, providing a great opportunity to replace the actual emissive critical raw materials.
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