Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 41, Issue 25, Pages 10737-10743Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2016.03.206
Keywords
H-2 evolution; MoS2; Nanosheets; Photocatalysis; Synthetic method
Categories
Funding
- NSF of China [51238002, 51272099, 51378246, 20801026]
- NSF of Jiangxi Province [KJLD12002, 20133ACB21001, 20122BCB23013, 20114BAB203005]
- Foundation of State Key Laboratory of Structural Chemistry [20100015]
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In this work, we reported a versatile and environmental-friendly mixed-solvent refluxing method to prepare MoS2 nanosheets with few layers by exfoliation of bulk MoS2 for the first time. The optimal synthetic conditions, including refluxing temperature, time and the volume ration of ethanol/water, were investigated according to the results of photo catalytic H-2 evolution from water splitting. The results show that the optimal conditions involve refluxing in 30% ethanol/water solution at 80 degrees C for 3 h. And the as-prepared MoS2 nanosheets show much better photocatalytic properties than bulk MoS2. The rate of photocatalytic H-2 evolution is 176.7 mu mol g(-1) h(-1) over the MoS2 nanosheets synthesized under the optimal conditions, whereas the rate of H2 production is only 21.8 mu mol g(-1) h(-1) over the bulk MoS2. In addition, some characterization studies demonstrate the MoS2 nanosheets have been successfully prepared by using the mixed-solvent refluxing method. The present work opens a new avenue to obtain two-dimensional nanosheets with single or few layers, such as the layered transition metal dichalcogenides. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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