Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 41, Issue 40, Pages 18121-18129Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2016.07.170
Keywords
Hydrogen storage; MgH2; Nanocrystalline Ni@C; Catalytic effects; Dehydrogenation/rehydrogenation
Categories
Funding
- National Natural Science Foundation of China [51501072, 51471089]
- Fund for Excellent Young and Middle-aged Scientists of Shandong Province [BS2014CL026]
- 111 Projects [B12015]
- Ministry of Education (MOE) [IRT-13R30]
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Nanocrystalline Ni@C was fabricated by a self-template strategy using benzimidazole as the reductant and carbon precursor, and it exhibited remarkable catalytic effect on hydrogen storage performances of magnesium hydride (MgH2). It was found that MgH2-Ni@C composites exhibited relatively lower sorption temperature, faster sorption kinetics, and more stable cycling performance than that of pure-milled MgH2. The desorption peak temperature was lowered down to 283 degrees C, i.e. of more than 74 degrees C, with respect to pure Mg hydride. For MgH2-Ni@C composites, a total of 6.2 wt% hydrogen was absorbed within 1 h at 300 degrees C. No obvious loss in absorption amount of MgH2-Ni@C composites can be seen after six cycles. An activation energy (E-a) of 103 kJ mol(-1) for MgH2-Ni@C has been obtained, which exhibited an improved kinetics. The presence of in situ synthesized Ni@C prevented the nanograins sintering and agglomeration of MgH2 during cycling, which enhanced dehydrogenation and cycling stability of MgH2-Ni@C composite. The synergetic effect of Ni active species and carbon contributed to the reduced hydrogenation/dehydrogenation temperatures and enhanced kinetics. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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