Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 41, Issue 48, Pages 22983-22990Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2016.09.182
Keywords
Transfer hydrogenation; Nitro compounds; Magnetic Pd catalysts; Ammonium formic
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Funding
- Special Fund for Basic Scientific Research of Central Colleges, South-Central University for Nationalities [CYZ2012005]
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Magnetic hydroxyapatite (HAP) supported Pd nanoparticles (gamma-Fe2O3@HAP-Pd) were used for the transfer hydrogenation of nitro compounds with HCOONH4 as hydrogen donors. Aniline was produced in an excellent yield (>99%) in water at 25 degrees C with 6 equiv. HCOONH4. This process is suitable to a wide range of nitro compounds with excellent yields for most cases. Both the HAP support and the Pd nanoparticles showed a synergistic effect on the transfer hydrogenation of nitro compounds. Furthermore, the gamma-Fe2O3@HAP-Pd catalyst was stable. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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