4.7 Review

Recent Development of Hierarchical Metal Oxides Based Gas Sensors: From Gas Sensing Performance to Applications

Journal

ADVANCED SUSTAINABLE SYSTEMS
Volume 6, Issue 4, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsu.202100370

Keywords

gas sensors; hierarchical structure; metal oxides; sensing performance

Funding

  1. National Natural Science Foundation of China [21771060, 61271126, 21776144, 51802167]
  2. International Science & Technology Cooperation Program of China [2016YFE0115100]
  3. Fundamental Research Funds in Heilongjiang Provincial Universities [135509308]
  4. Program for Science and Technology Project of Heilongjiang province [JQ2021B002]
  5. Reform and Development Fund Project of Local University - Central Government, Heilongjiang Touyan Innovation Team Program

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This article reviews the development of metal oxide-based gas sensors, focusing on hierarchical sensing materials. The authors discuss the design strategy, application fields, sensing mechanisms, and research advances for different gases. They also explore the future prospects and challenges of hierarchical metal oxide-based gas sensors.
Gas sensors based on metal oxides have attracted wide attention, due to their inherent advantages such as low cost, small size, fast response, and easy usage. Recently, much effort have been put into the design of metal oxide-based sensing materials to further improve the performance of gas sensors. Among them, the fabrication of hierarchical metal oxide-based sensing materials has become the most attractive strategy. In this article, the authors widely review the last decade of development of hierarchical metal oxide-based gas sensors, in which several representative gases including formaldehyde, acetone, H2S, amines, and water are chosen as the analytes to discuss in depth. The application fields cover indoor air quality monitoring, breath analysis, and food quality and safety. The research advances for each gas is summarized from the perspective of excellent sensing performance in terms of low operating temperature and detection limit, high selectivity, fast responses, and humidity independent responses. Furthermore, the accepted sensing mechanism of metal oxide-based gas sensors and widely used technology to verify these mechanisms are both included. Finally, the outlook and challenges for future investigations of hierarchical metal oxide-based gas sensors are also discussed from the perspectives of theory and practice.

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