Journal
MATERIALS TODAY ENERGY
Volume 22, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.mtener.2021.100872
Keywords
Proton intercalation; Crystalline quinones; Organic electrode; Proton batteries; Aqueous battery
Funding
- Ministry of Education, Singapore, under its MOE tier2 grant [MOE2019-T2-1-181]
- 111 Project [D20015]
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This study demonstrates the reversible intercalation and deintercalation of protons in crystalline 2,6-dihydroxyanthraquinone (DHAQ), which is utilized in a rechargeable proton battery system with high capacity retention rate. Furthermore, the morphology evolution from particulate DHAQ into centimeter-scale nanofibers is observed during battery cycling.
As a class of redox-active compounds, anthraquinones (AQs) have been investigated in rechargeable metallic ion batteries. In this work, it is found that protons (H+) can be reversibly intercalated and deintercalated in crystalline 2,6-dihydroxyanthraquinone (DHAQ) at a potential of -0.21 V vs. Ag/AgCl in acidic solution and exhibits a specific capacity of 110 mAh g(-1). This unique property is leveraged in a rechargeable proton battery system with a DHAQ anode and an Mn2+ cathode. During battery cycling, a morphology evolution from particulate DHAQ into centimeter-scale nanofibers is observed. It is revealed that the evolution of morphology stems from a realignment of the DHAQ molecule. The quinone proton battery delivers an equilibrium voltage of 1.1 V, and the capacity retention rate could be as high as 100% after 2600 cycles. This study showcases a unique proton (de)intercalation chemistry in crystalline AQ and demonstrates the viability of the organic proton battery system. (C) 2021 Elsevier Ltd. All rights reserved.
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