4.7 Article

ADA′DA small molecule acceptors with non-fully-fused core units

Journal

MATERIALS CHEMISTRY FRONTIERS
Volume 6, Issue 6, Pages 802-806

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1qm01622a

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Funding

  1. Songshan Lake Materials Laboratory [2021SLABFK02]
  2. National Key Research and Development Program of China [2017YFA0206600]
  3. National Natural Science Foundation of China [51773045, 21772030, 51922032, 21961160720]

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Two non-fully-fused core unit acceptors, IDTBT-4F and IDTP-4F, showed good performance in organic solar cells.
Two ADA ' DA small molecule acceptors, IDTBT-4F and IDTP-4F, with non-fully-fused core units were developed. The DA ' D core units were facilely prepared via Stille coupling of D and A ' fused-ring building blocks. IDTBT-4F and IDTP-4F show banana-shaped molecular configurations and good planarity. When blending with a wide-bandgap polymer donor L1-S, IDTBT-4F and IDTP-4F delivered decent PCEs of 12.00% and 11.92%, respectively, in organic solar cells.

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